Human and ecotoxicological risk assessment of heavy metals in polymer post treatment sludge from Barekese Drinking Water Treatment Plant, Kumasi.

The disposal of polymer post-treatment sludge (PTS) from Barekese Water Treatment Plants (WTPs) as organic fertilizer and aquatic feed is a common practice in Ghana, necessitating a thorough evaluation of its ecological and human health risks. This study aims to assess the suitability of PTS samples for soil amendment and fish feed, scrutinizing potential hazards to consumer health and soil. PTS samples were collected from five distinct lateral sections of three clariflocculator tanks. Potentially toxic metals such as Cd, Zn, Pb, Cu, Ni, and Cr were determined using a flame atomic absorption spectrophotometer. The mean concentration of 7.82 ± 2.43, 0.31 ± 0.021, and 0.78 ± 0.042 mg/kg for Mn, Zn, and Pb respectively. The concentrations of Ni, Cr, and Cd were below their detection limits (BDL) in all PTS samples. Upon detailed exposure assessment, ingestion emerged as the primary exposure route for both adults and children, with non-cancer risks (NCR) determined to be below 1 for both age groups. Additionally, an exploration of potential cancer risks (CR) associated with heavy metal exposure in the PTS samples revealed values below the tolerable intake levels ranging from 10-4 to 10-6 for both adults and children (10-8 and 10-9, respectively). This study also employs various ecological indices, such as Nemerow's synthetic pollution index (PN), single factor pollution index (PI), geo-accumulation index (Igeo), contamination factor (CF), potential ecological risk index (PERI), pollution load index (PLI), polymetallic contaminant index (IPD), and ecological risk index (ERI). These indices consistently highlight a low contamination status and ecological sensitivity. Consequently, the study indicates that the presence of metals in the PTS samples does not pose a significant threat to the surrounding environment and human health. Furthermore, this research underscores the inadequacy of relying solely on regulatory limit values in assessing the health risks of waste materials. Such comprehensive assessments are crucial for safeguarding aquatic and human populations.

Investigation of fluoride concentrations, water quality, and non-carcinogenic health risks of borehole water in bongo district, northern Ghana.

Access to potable water is a significant concern due to the increasing global threat posed by fluoride contamination in groundwater sources. This study investigated the concentrations of fluoride (F-), the suitability of groundwater for human consumption, the physicochemical characteristics affecting the water quality, and non-carcinogenic adverse health risks to both children and adults in the Bongo district in Northern Ghana. The findings revealed that the groundwater had a mean pH, salinity, TDS, conductivity, and turbidity below the WHO guideline values with a mean fluoride concentration of 1.76 mg/L above the guideline limit of 1.5 mg/L. The study also found that there was no strong relationship between fluoride and the measured water parameters, which may be attributed to poor control of distribution, transport mechanisms, and sources. The WQI scores ranged from 42.62% to 70.72%, indicating that all borehole water samples were of good and excellent quality. The average chronic daily intake showed that children are often more exposed to the harmful impact of fluoride than adults. The average HQ > 1 indicates the probability of dental and skeletal fluorosis after continuous exposure over time in adults and children. The study recommends taking immediate action to mitigate high groundwater fluoride concentrations, implementing appropriate water management strategies, and raising public awareness of the health risks. These measures can guide future groundwater management practices and help policymakers address contamination and protect local communities.